Bis(tetraphenylphosphonium) tris[N-(methylsulfonyl)dithiocarbimato(2−)-κ2 S,S′]stannate(IV)
نویسندگان
چکیده
In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal occupancy. In the crystal structure, weak inter-molecular C-H⋯O and C-H⋯S inter-actions contribute to the packing stabilization.
منابع مشابه
Bis(tetraphenylphosphonium) bis[N-(2,5-dichlorophenylsulfonyl)dithiocarbimato(2−)-κ2 S,S′]platinate(II)
In the title salt, (C(24)H(20)P)(2)[Pt(C(7)H(3)Cl(2)NO(2)S(3))(2)], the Pt(II) ion (site symmetry ) is coordinated by two S,S'-bidentate N-(2,5-dichloro-phenyl-sulfon-yl)dithio-carbimate ligands, resulting in a slightly distorted PtS(4) square-planar geometry. In the crystal, a C-H⋯O inter-action is observed, as well as electrostatic attraction between the oppositely charged ions.
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009